Osprey® CE alloys comprise a range of mainly binary hyper-eutectic silicon-aluminium alloys (note – not AlSiC composites) where increasing silicon content results in lower expansion coefficients and increasing specific stiffness.
The table shows our standard range of CE alloys. Mechanical and thermal properties for the alloys are found in separate tables below.
Designation system for Osprey® alloys
The designations for CE alloys are constructed using the following model:
- CE stands for Controlled Expansion.
- The number following after 'CE' (e.g. 7 in CE7F) gives the room temperature CTE in ppm/°C.
- The M grade alloys (CE17MF and CE13MF) contain small additions of iron (Fe), manganese (Mn) and magnesium (Mg) so that similar heat treatment to 6000 series alloys (Al-Si-Mg) produces hardening of the matrix.*
*Originally, this was to improve the machinability of the alloys but it can also be used to improve the strength, but at the expense of thermal conductivity.
Osprey® alloy | CTE, ppm/°C | Al/Si ratio, % |
---|---|---|
CE17F | 17 | 73/27 |
CE17MF | 17 | 73/27 |
CE15F* | 15 | 65/35 |
CE13F | 13 | 58/42 |
CE11F | 11 | 50/50 |
CE9F | 9 | 40/60 |
CE8F* | 8 | 35/65 |
CE7F | 7 | 30/70 |
CE6F | 6 | 20/80 |
CE5F* | 5 | 13/87 |
*Contact us for more data about this alloy
Mechanical properties
CE17F | CE17MF | CE13F | CE11F | CE9F | CE7F | CE6F | |
---|---|---|---|---|---|---|---|
Composition | Al-27%Si | Al-27%Si | Al-42%Si | Al-50%Si | Si-40%Al | Si-30%Al | Si-20%Al |
Tensile strength, ultimate | ≥160 | 175-3123) | 205 | 193 | 181 | ≥100 | N/A |
Yield strength, MPa | 100 | 282 | 147 | 189 | - | - | N/A |
Bend strength (three point), Mpa | - | - | 300 | 300 | 300 | 270 | 3191) |
Young's modulus, GPa | 91.8 | 91.82) | 101.9 | 121.4 | 118 | 129.2 | 130 |
Rigidity modulus, GPa | 35.8 | 35.82) | 42.22) | 48.6 | 46 | 51.6 | N/A |
Poisson's ratio | 0.28 | 0.282) | 0.272) | 0.29 | 0.29 | 0.26 | N/A |
Density, g/cc | 2.6 | 2.6 | 2.55 | 2.51 | 2.47 | 2.43 | 2.352) |
Hardness, Hv | 60 | 75–1323) | 90 | - | 230 | - | N/A |
1) Test pieces 4 mm x 3 mm x 40 mm
2) Calculated values
3) Depending on heat-treatment condition
Thermal properties
CE17F | CE17MF | CE13F | CE11F | CE9F | CE7F | |
---|---|---|---|---|---|---|
Composition1) | Al-27%Si | Al-27%Si | Al-42%Si | Al-50%Si | Si-40%Al | Si-30%Al |
100K–200K | - | - | - | 7.8 | - | - |
200K–300K | - | - | - | 10.6 | - | - |
100K–300K | - | - | - | 9.2 | - | - |
-60–200ºC | - | - | - | 11.6 | - | 7.6 |
Room temp. | 15.3 | 15.3 | 12.2 | 11.4 | 9.1 | 7.2 |
25–200ºC | 17.1 | 17.1 | 13.7 | 12.3 | 10.2 | 8.3 |
25–300ºC | 18.1 | 18.1 | 14.6 | 12.9 | 10.9 | 8.8 |
25–400ºC | 18.7 | 18.7 | 15.2 | 13.4 | 11.3 | 9.2 |
25–500ºC | 19 | 19 | 15.5 | 13.7 | 11.4 | 9.7 |
CE17F | CE17MF | CE13F | CE11F | CE9F | CE7F | |
---|---|---|---|---|---|---|
Composition1) | Al-27%Si | Al-27%Si | Al-42%Si | Al-50%Si | Si-40%Al | Si-30%Al |
At -100ºC | - | - | - | - | - | 180 |
At -50ºC | - | - | - | - | 1292) | 140 |
At -0ºC | - | - | - | - | - | 135 |
At 25ºC | 177.4 | 146.8 | 145 | 132 | 121 | 120 |
At 50ºC | - | - | - | - | - | 110 |
At 100ºC | - | - | - | - | 125* | 110 |
At 200ºC | 151.2 | 146.5 | - | - | 108* | 100 |
At 300ºC | - | - | - | - | 98* | 88 |
At 400ºC | - | - | - | - | 90* | 80 |
At 500ºC | - | - | - | - | 85* | 75 |
Specific heat, J/kgºC | 846.3 | 767.25 | 857* | 754* | 780* | 785* |
* Calculated values
Microstructure
In the molten state Si and Al are mutually soluble, whereas in the rapidly solidified condition there is minimal solubility of Si in Al (< 0.3%) and even less solubility of Al in Si. The products are true alloys rather than metal-matrix composites (such as AlSiC) as all the phases present originate from an homogeneous melt.
The Al phase is continuous up to ~ 85%Al. Over approximately 40% Si, the Si phase also becomes continuous, offering a co-continuous duplex alloy (similar to AlBe alloys).
The continuous Si phase produces a stiff alloy with low thermal expansion and low internal stresses, whereas the continuous Al phase enhances thermal conductivity and toughness and lowers electrical resistance.
Consequently, as the Al content is increased, electrical conductivity, thermal conductivity, strength, toughness, CTE and machinability are also increased. For these reasons, it is best to choose the highest Al content alloy that is acceptable for the application.
Although Sandvik can supply machined components with Si contents as high as 85% Si (i.e. CE5F), the relative brittleness of this composition means whenever feasible it is often better to compromise on the exact expansion match required and use a lower Si content alloy. For example, Kovar®* packages (with a CTE of ~ 7ppm/°C) have been successfully replaced with CE9F, CE11F and even CE13F.
* Kovar is a trademark of Carpenter Technology Corporation
The coefficient of thermal expansion (CTE) for Osprey® CE alloys range from 5 to 17 ppm/K. The graph shows the CTE for two of our most common alloys.
Main characteristics of CE alloys
- Controlled thermal expansivity:
5–17 ppm/°C - Low density: < 2.5 gm/cc
- High thermal conductivity:
120–180 W/m K - High specific stiffness:
39 to 54 x103 Nm/g - Machinable, plateable and weldable